JPH0138805B2 - - Google Patents
Info
- Publication number
- JPH0138805B2 JPH0138805B2 JP6299886A JP6299886A JPH0138805B2 JP H0138805 B2 JPH0138805 B2 JP H0138805B2 JP 6299886 A JP6299886 A JP 6299886A JP 6299886 A JP6299886 A JP 6299886A JP H0138805 B2 JPH0138805 B2 JP H0138805B2
- Authority
- JP
- Japan
- Prior art keywords
- ion
- polymer composition
- dopant
- polymer
- integer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000642 polymer Polymers 0.000 claims description 39
- -1 hexafluorophosphate ion Chemical class 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 33
- 239000000178 monomer Substances 0.000 claims description 16
- 239000002019 doping agent Substances 0.000 claims description 13
- 229920001940 conductive polymer Polymers 0.000 claims description 9
- 239000003115 supporting electrolyte Substances 0.000 claims description 7
- 150000003577 thiophenes Chemical class 0.000 claims description 5
- 150000001450 anions Chemical class 0.000 claims description 4
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Chemical compound [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 238000006116 polymerization reaction Methods 0.000 description 13
- 239000000463 material Substances 0.000 description 10
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 8
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 7
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 229930192474 thiophene Natural products 0.000 description 6
- JEDHEMYZURJGRQ-UHFFFAOYSA-N 3-hexylthiophene Chemical compound CCCCCCC=1C=CSC=1 JEDHEMYZURJGRQ-UHFFFAOYSA-N 0.000 description 5
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 239000004020 conductor Substances 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QENGPZGAWFQWCZ-UHFFFAOYSA-N 3-Methylthiophene Chemical compound CC=1C=CSC=1 QENGPZGAWFQWCZ-UHFFFAOYSA-N 0.000 description 2
- RFKWIEFTBMACPZ-UHFFFAOYSA-N 3-dodecylthiophene Chemical compound CCCCCCCCCCCCC=1C=CSC=1 RFKWIEFTBMACPZ-UHFFFAOYSA-N 0.000 description 2
- WQYWXQCOYRZFAV-UHFFFAOYSA-N 3-octylthiophene Chemical compound CCCCCCCCC=1C=CSC=1 WQYWXQCOYRZFAV-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 229910003437 indium oxide Inorganic materials 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6299886A JPS62220517A (ja) | 1986-03-20 | 1986-03-20 | 導電性重合体組成物及びその製造方法 |
| US07/028,620 US4737557A (en) | 1986-03-20 | 1987-03-20 | 3-N-higher alkylthiophene polymer and composition thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6299886A JPS62220517A (ja) | 1986-03-20 | 1986-03-20 | 導電性重合体組成物及びその製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62220517A JPS62220517A (ja) | 1987-09-28 |
| JPH0138805B2 true JPH0138805B2 (en]) | 1989-08-16 |
Family
ID=13216552
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6299886A Granted JPS62220517A (ja) | 1986-03-20 | 1986-03-20 | 導電性重合体組成物及びその製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62220517A (en]) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2596566B1 (fr) * | 1986-04-01 | 1989-03-10 | Solvay | Polymeres conducteurs derives de 3-alkylthiophenes, procede pour leur fabrication et dispositifs electroconducteurs les contenant |
| JPH02202514A (ja) * | 1989-01-31 | 1990-08-10 | Nippon Oil & Fats Co Ltd | フルオロアルキル基含有ヘテロ芳香族系重合体 |
| JPH02292872A (ja) * | 1989-05-02 | 1990-12-04 | Agency Of Ind Science & Technol | 安定化半導体電極の製造方法 |
| JPH03210326A (ja) * | 1990-01-13 | 1991-09-13 | Dainippon Printing Co Ltd | 導電性高分子化合物及びその製造方法 |
-
1986
- 1986-03-20 JP JP6299886A patent/JPS62220517A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62220517A (ja) | 1987-09-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0804497A1 (en) | Soluble, electroconductive polypyrrole and method for preparing the same | |
| Gal et al. | Synthesis and characterization of an ionic conjugated polymer: Poly [2‐ethynyl‐N‐(2‐thiophenecarbonyl) pyridinium chloride] | |
| US4663001A (en) | Electroconductive polymers derived from heterocycles polycyclic monomers and process for their manufacture | |
| US5069823A (en) | Thiophene compound and method for production thereof | |
| JPH0138805B2 (en]) | ||
| EP0231309B1 (en) | Process for manufacturing electrically conductive polythiophene | |
| JPS6411209B2 (en]) | ||
| JPH02218716A (ja) | 有機半導体及びその製造方法 | |
| JPH0138411B2 (en]) | ||
| JPS63205316A (ja) | 有機半導体材料の製造方法 | |
| Alakhras | Electrosynthesis of poly (selenophene-co-thiophene) films in boron trifluoride diethyl etherate/ethyl ether | |
| Jeon et al. | Electrochemical doping of poly (3-vinylperylene) and electrical properties of doped polymers | |
| CN113161471B (zh) | 热电转换元件和具有热电转换元件的物品 | |
| JPH02255718A (ja) | 導電性共重合体組成物及びその製造方法 | |
| JPH06104716B2 (ja) | 導電性重合体組成物及びその製造方法 | |
| JPS61254620A (ja) | ナフト〔２，３―ｃ〕チオフェン構造を有する重合体の製造方法 | |
| Xu et al. | Low potential electrodeposition of high‐quality and freestanding poly (3‐(6‐bromohexyl) thiophene) films | |
| JPH11106484A (ja) | チオフェン構造を有する共重合体およびその製造方法 | |
| JPS6162520A (ja) | 電導性高分子の製造方法 | |
| CN1047392C (zh) | 含氟烷氧基及含氟烷醚基取代聚噻吩及其聚合方法及应用 | |
| JPH02255717A (ja) | チオフェン系共重合体及びその製造方法 | |
| JPH0412725B2 (en]) | ||
| JPH029621B2 (en]) | ||
| JPH0275625A (ja) | 導電性重合体 | |
| David et al. | Synthesis and Applications of Conducting Polymers–An Overview |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |